This was 0.3 percent higher than the state average of 46.3 percent. In 2020 the total municipality population reached 544.
92.1 percent of the population had at least a high school diploma or the equivalent.
Degree distribution in Unionville for 2020*
| Degree | Number of people | Percentage of population |
|---|---|---|
| No degree | 28 | 7.9 |
| Regular high school diploma | 81 | 22.9 |
| GED or alternative credential | 27 | 7.6 |
| Some college, less than 1 year | 23 | 6.5 |
| Some college, 1 or more years, no degree | 30 | 8.5 |
| Associate's degree | 43 | 12.1 |
| Bachelor's degree | 42 | 11.9 |
| Master's degree | 28 | 7.9 |
| Professional school degree | 52 | 14.7 |
| Doctorate degree | 0 | 0 |
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